Rounding an Edge

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Chamfer an edge once, then select the two new edges and chanfer again but adjust the chamfer value to about 40% of the first.

e.g. 5 first time, 2 second time.

Anyone know of a simple way to get a round edge on a corner? Just point me in the right direction. I would like to round a corner similar to the way the chamfer method works on a primitive cube.

Thakns, Greg Davies